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If it's just for a flash shield it should work just fine as long as it's not right where the welding is taking place. Leave enough room that sparks and heat don't get on it. Several feet away from work area, if you are worried about flash blinding someone it should do OK.
It would be to protect little one inside the house and be several feet from welding. Are the semi-transparent plastic welding shield better? Would they protect the eyes of someone happen to be caught watching?